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Full results from Free Practice 1 from the Formula 1 Mexico City Grand Prix at Autódromo Hermanos Rodríguez.
| Pos | Num | Driver | Team | Laps | Best | Diff |
| 1 | 63 | George Russell | Mercedes | 23 | 1:17.998 | |
| 2 | 55 | Carlos Sainz | Ferrari | 25 | 1:18.315 | 0.317 |
| 3 | 22 | Yuki Tsunoda | RB | 24 | 1:18.699 | 0.701 |
| 4 | 1 | Max Verstappen | Red Bull Racing | 14 | 1:18.839 | 0.841 |
| 5 | 27 | Nico Hulkenberg | Haas | 18 | 1:18.904 | 0.906 |
| 6 | 81 | Oscar Piastri | McLaren | 24 | 1:18.958 | 0.960 |
| 7 | 31 | Esteban Ocon | Alpine | 22 | 1:18.996 | 0.998 |
| 8 | 77 | Valtteri Bottas | Sauber | 23 | 1:19.048 | 1.050 |
| 9 | 30 | Liam Lawson | RB | 25 | 1:19.093 | 1.095 |
| 10 | 11 | Sergio Perez | Red Bull Racing | 22 | 1:19.094 | 1.096 |
| 11 | 43 | Franco Colapinto | Williams | 21 | 1:19.109 | 1.111 |
| 12 | 12 | Kimi Antonelli | Mercedes | 18 | 1:19.200 | 1.202 |
| 13 | 29 | Pato O’Ward | McLaren | 21 | 1:19.295 | 1.297 |
| 14 | 20 | Kevin Magnussen | Haas | 22 | 1:19.335 | 1.337 |
| 15 | 10 | Pierre Gasly | Alpine | 20 | 1:19.340 | 1.342 |
| 16 | 18 | Lance Stroll | Aston Martin | 18 | 1:19.600 | 1.602 |
| 17 | 23 | Alex Albon | Williams | 7 | 1:19.812 | 1.814 |
| 18 | 34 | Felipe Drugovich | Aston Martin | 17 | 1:19.819 | 1.821 |
| 19 | 97 | Robert Schwartzman | Sauber | 18 | 1:19.988 | 1.990 |
| 20 | 38 | Oliver Bearman | Ferrari | 7 | 1:21.256 | 3.258 |
